In reply to freeflyer:
Thanks all for your help. Just replying here to close the loop in case someone else has a similar problem in the future, and as I did, searches the forum for advice:
Its difficult to say exactly what the problem was, but certainly the out of date versions of Explorer and windows contributed. That being said, once I'd updated to the latest versions and all updates on both, the problem still persisted. The final step was to try to connect via my phone hot spot, identifying the problem with my ISP. Removing all parental controls was the final part of the puzzle. Note that clarifying that the PC and the website sat outside of these, had no effect.
Thanks again to all that posted, including the UKC team.
Sven