In reply to Jamie Wakeham:
I design and install these systems as part of my job, so can advise on this.
First note, is keep it simple, do not try and do the thermal store wood burner thing, I've seen it tried and it never work as well as a simple efficient system. Systems with lots of inputs are complex and lack efficiency.
As s rule, get a Monobloc unit with an unvented cylinder. Connect this to UFH or Radiators designed to run at 40 degrees.
The Mitsubishi Ecodan with its own cylinder is by far the best and most refined unit we have dealt with. However like all heat pumps , it needs to be installed correctly or you won't get it to perform as it should. All the horror stories you read are usually badly installed systems using poor quality products.
The first thing to work on should be the insulation in the house, concentrating on the details and edges everyone misses out. By reducing the heat loss, you reduce you bills going foward, and make any system work better.
When they are done right, heat pumps with low temperature heat emitters, are by far the most comfortable way to heat your house.