These devices all depend on your current behaviour when it comes to heating, if you avoid automatic mode and turn it on when you come home and off when you leave (and never forget this step) then the savings will be negligible.
If you currently make use of the automatic scheduling and end up heating your empty house when you are at the wall/working late/dinner out etc. then the savings can be reasonable per year, maybe £50-£100 depending on the insulation, house size etc.
If you are currently in the second group then the savings plus other benefits are worth considering IMO.